PHPA Polymer Liquid
Part No. RXSOL-34-8186-025
PHPA CO-Polymer
RXSOL PHPA is high molecular weight polymers one of the most Popular Drilling Polymers in the Oilfield Industry.
Key details
| Part number | RXSOL-34-8186-025 |
|---|---|
| Generic name | PHPA CO-Polymer |
| Available pack sizes | PHPA Liquid is available in 25Kg Pails, 50 Kg, 220 Kg or IBC Tanks, Shrink-wrapped and well palletized. |
| Supply locations | 2-Acrylamido 2-methylpropanesulfonic Acid ATBS manufacturer supplier distributor in Mumbai, Kandla, Kolkata, Vizag, Chennai, India, Fujairah, Dubai, Sharjah, UAE, Gulf, Middle East, Muscat Oman, Kenya Africa. Get the best quality of 2-Acrylamido 2-methylpropanesulfonic Acid ATBS at a competitive price from us. We have ready stock of 2-Acrylamido 2-methylpropanesulfonic Acid ATBS in India, UAE Gulf, Oman, Kenya Africa. Contact us for bulk as well as small orders. |
| Usage unit | Kg |
| Quantity per unit | 25 |
Need this product at your port or plant?
Enquire NowPARTIALLY HYDROLYSED POLYACRYLAMIDE (PHPA) manufactured by RXSOL manufacturing Plant in Mumbai, RXSOL PHPA is high molecular weight polymers one of the most Popular Drilling Polymers in the Oilfield Industry. Polymerised product of 2-Acrylamido 2-methylpropanesulfonic acid which is high molecular weight polymers (greater than two million) are desired.
PHPA LIQUID is a multifunctional high molecular weight PHPA copolymer in revert emulsion form. It can provide rapid viscosity development without the mixing problems. It is also used to encapsulate drill cuttings, lubricate wellbore and stabilize shale in low solids and non-dispersible drilling fluids systems.
PHPA specialized for oil & gas drilling and drilling-fluid applications.
Our PHPA (Partially Hydrolyzed Polyacrylamide) is used in drilling fluids for applications such as shale inhibition, borehole stability and fluid-loss control as drilling fluids / oilfield chemicals.
PHPA is a co-polymer of anionic character and high molecular weight. very strong ionic group and ionizes completely in aqueous solutions. In applications where the precipitation of mineral salts is undesirable, the incorporation of a polymer containing even a small quantity of AMPS can significantly inhibit the precipitation of divalent cations. It is a water-soluble polymer, which is primarily used as a highly efficient fluid loss reducer, Viscosifier and protective colloid for shale’s and cutting in fresh water, calcium, sodium brines and KCL mud systems. It is compatible with most of the drilling fluid products, biopolymers, PAC, CMC. It maintains borehole stability by preventing shale swelling and erosion.
The normal application is 1.75 to 3.5 lb/bbl used in combination with KCl Potassium Chloride at 3 - 8% provides effective inhibition.
|
PARAMETERS |
SPECIFICATIONS |
|
Appearance Non-Volatile Matter Colour APHA (25% Aq.solution) Iron Inhibitor (MMEHQ) |
Viscous Liq Clear Colourless To Loght Yellow Liquid 99.0 % Min. 100 Max. 10 ppm Max. 65-90 ppm |
| Charge | Anionic |
| Sp. Gravity | 1.05 to 1.1 |
| Product Name | PHPA Polymer Liquid |
| Part Number | RXSOL-34-8186-025 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
| Phone | +91 22 20871200 - 1400 |
| Fax | +91 22 27612100 :::AOH :0091 9821214367 |
| mail @ rxmarine.com | |
| Website | www.rxmraine.com |
| Chemical Name | CAS | EC number | Weight | Formula |
| 2-Acrylamido 2-methylpropanesulfonic Acid | 15214-89-8 | 239-268-0 | 10-20 | C7H13NO4S |
| Proprietory Blend with Catlyst | --- | --- | 30-40 | --- |
| Signal Word | Danger |
| Hazard Statements | H302 + H332 Harmful if swallowed or if inhaled. H318 Causes serious eye damage. H335 May cause respiratory irritation. |
| Precautionary statements | P261 Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray. P264 Wash skin thoroughly after handling. P280 Wear eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
| Classification of the substance or mixture | Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008. |
| Supplemental Hazard Statements | None. |
| Other hazards | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| General advice | Show this material safety data sheet to the doctor in attendance. |
| If inhaled | After inhalation: fresh air. |
| Eye Contact | After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses. |
| Swallowed | After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
| Skin Contact | In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. |
| Inhalation | Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary. |
| Ingestion | Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
| Most important symptoms and effects, both acute and delaye | The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11 |
| Indication of any immediate medical attention and special treatment needed | No data available |
| Flammability | May be combustible at high temperature. |
| Suitable extinguishing media | Water Foam Carbon dioxide (CO2) Dry powder |
| Unsuitable extinguishing media | For this substance/mixture no limitations of extinguishing agents are given. |
| Special hazards arising from the substance or mixture | Carbon oxides Nitrogen oxides (NOx) Sulfur oxides Combustible. Fire may cause evolution of: nitrogen oxides, Sulfur oxides Development of hazardous combustion gases or vapours possible in the event of fire. |
| Further information | Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
|
Hazardous combustion products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
| Advice for firefighters | In the event of fire, wear self-contained breathing apparatus. |
| Protective Equipment | Use personal protective equipment. |
| Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen. Ambient fire may liberate hazardous vapours. |
| Personal precautions, protective equipment and emergency procedures | Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8. |
| Spillage | Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
| Personal Protection | Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
| Enviromental Precaution | Do not let product enter drains. |
|
Methods and materials for containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts. |
| Advice on protection against fire and explosion | Provide appropriate exhaust ventilation at places where dust is formed. |
| Incompatible materials | Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
| Hygiene measures | Change contaminated clothing. Preventive skin protection recommended. Wash hands after working with substance. For precautions see section 2.2. |
| Precautions for safe handling | Work under hood. Do not inhale substance/mixture. |
| Conditions for safe storage, including any incompatibilities | Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
| Storage conditions | Tightly closed. Dry. Recommended storage temperature see product label. |
| Storage class | Storage class (TRGS 510): 13: Non Combustible Solids |
| Specific end use(s) | Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
| Advice on general occupational hygiene | Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
| Requirements for storage | Keep in cool and store under shade. |
| Exposure controls | No specific additional engineering controls are required. Provide good natural or artificial ventilation. |
| Engineering Control | Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
| Eye/face protection | Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles |
| Body Protection | Protective clothing |
| Skin protection | This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,11 mm Break through time: 480 min Material tested:KCL 741 Dermatril® L |
| Respiratory protection | Required when dusts are generated. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. Recommended Filter type: Filter type P2 The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
| Other Protection Measure | Handle in accordance with good industrial hygiene and safety practice. |
| Control of environmental exposure | Do not let product enter drains. |
|
PARAMETERS |
SPECIFICATIONS |
|
Appearance Non-Volatile Matter Colour APHA (25% Aq.solution) Iron Inhibitor (MMEHQ) |
Viscous Liq Clear Colourless To Loght Yellow Liquid 99.0 % Min. 100 Max. 10 ppm Max. 65-90 ppm |
| Charge | Anionic |
| Sp. Gravity | 1.05 to 1.1 |
| Odour | No data available |
| Odor Threshold | Not Applicable |
| Boiling Point | No data available |
| Flash Point | No data available |
| Evaporation Rate | Not Applicable |
| Flammability (solid, gas) | No data available |
| Explosive limits | No Data Available |
| Upper/lower flammability or explosive limits | No data available |
| Autoignition temperature | > 400 °C at 1013,250 hPa |
| Decomposition temperature | No data available |
| Viscosity,kinematic | No data available |
| Vapour pressure | 0,1 hPa at 25 °C |
| Relative Vapour Density | No data available |
| Freezing point | No data available |
| Specific Gravity | No data available |
| Partition coefficient | 3,7 at 20 °C |
| Explosive properties | No data available |
| Solubility | Fully Soluble |
| Ignition temperature | No information available. |
| Particle characteristics | No data available |
| Reactivity | The following applies in general to flammable organic substances and mixtures: in correspondingly fine distribution, when whirled up a dust explosion potential may generally be assumed. |
| Stability | The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): hydroquinone monomethyl ether (0,0002 %) |
| Possibility of hazardous reactions | Violent reactions possible with: Strong oxidizing agents strong alkalis with Water polymerization |
| Conditions to avoid | No data available |
| Incompatible materials | No data available |
| Hazardous Polymerization | In the event of fire: see section 5 |
| Acute toxicity | Acute toxicity estimate Oral - 1.831 mg/kg (Calculation method) LD50 Oral - Rat - male - 1.830 mg/kg (OECD Test Guideline 401) Acute toxicity estimate Inhalation - 4 h - 1,51 mg/l - dust/mist(Calculation method) Acute toxicity estimate Inhalation - 1,51 mg/l - dust/mist (Expert judgment) Symptoms: Possible damages:, mucosal irritations Dermal: No data available |
| Skin corrosion/irritation | Skin - Rabbit Result: No skin irritation - 24 h Remarks: (ECHA) |
| Serious eye damage/eye irritation | Eyes - Rabbit Result: Eye irritation Remarks: (ECHA) |
| Respiratory or skin sensitization | Buehler Test - Guinea pig Result: negative Remarks: (ECHA) |
| Carcinogenicity | No data available |
| Germ cell mutagenicity | Test Type: Mutagenicity (mammal cell test): chromosome aberration. Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: Positive results were obtained in some in vitro tests. Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Chromosome aberration test Species: Rat Cell type: Bone marrow Application Route: Oral Method: OECD Test Guideline 475 Result: negative |
| Reproductive toxicity | No data available |
| Specific target organ toxicity - single exposure | Inhalation - May cause respiratory irritation. - Lungs Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
| Special Remarks on other Toxi Effects on Humans | Eyes - Rabbit Result: No eye irritation (OECD Test Guideline 405) |
| Additional Information | Material is extremely destructive to tissue of the mucous membranes and upper respiratory tract, eyes, and skin., Cough, Shortness of breath, Headache, Nausea, To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated. Other dangerous properties can not be excluded. Handle in accordance with good industrial hygiene and safety practice. |
| Persistence and degradability | Biodegradability aerobic - Exposure time 44 d Result: 10 % - Not readily biodegradable. |
| Bioaccumulative potential | No data available |
| Toxicity to fish | Static test LC50 - Lepomis macrochirus (Bluegill sunfish) - 170 mg/l - 96 h (US-EPA) |
| Toxicity to daphnia and other aquatic invertebrates | Static test EC50 - Daphnia magna (Water flea) - 340 mg/l - 48 h (US-EPA) |
| Toxicity to algae | Static test NOEC - Pseudokirchneriella subcapitata - 2.000 mg/l - 96 h (OECD Test Guideline 201) |
| Toxicity to bacteria | Respiration inhibition NOEC - activated sludge - 1.000 mg/l - 3 h (OECD Test Guideline 209) |
| Mobility in soil | No Information available |
| Results of PBT and vPvB assessment | This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
| Endocrine disrupting properties | The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. |
| Other adverse effects | Discharge into the environment must be avoided. |
| Disposal methods | The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
| Contaminated packaging | Dispose of as unused product. |
| Waste treatment Method | See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
| UN number | ADR/RID: IMDG: IATA: |
| UN proper shipping name | ADR/RID: IMDG: IATA: |
| Transport hazard class(es) | ADR/RID: IMDG: IATA: |
| Packaging group | ADR/RID: IMDG: IATA: |
| Environmental hazards | ADR/RID: No IMDG: No IATA: NO |
| Special precautions for user | Tunnel restriction code : (C/E) |
| Further information | Not classified as dangerous in the meaning of transport regulations. |
| Transport in bulk according to IMOinstruments | No data available |
| Inventory status | Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65. |
| Safety, health and environmental regulations/legislation specific for the substance or mixture | This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006. |
| Other regulations | Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work. |
| Chemical Safety Assessment | For this product a chemical safety assessment was not carried out |
| Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages. DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. |
|
PARAMETERS |
SPECIFICATIONS |
|
Appearance Non-Volatile Matter Colour APHA (25% Aq.solution) Iron Inhibitor (MMEHQ) |
Viscous Liq Clear Colourless To Loght Yellow Liquid 99.0 % Min. 100 Max. 10 ppm Max. 65-90 ppm |
| Charge | Anionic |
| Sp. Gravity | 1.05 to 1.1 |
The normal application is 1.75 to 3.5 lb/bbl used in combination with KCl Potassium Chloride at 3 - 8% provides effective inhibition.
2-Acrylamido 2-methylpropanesulfonic acid USES and Application :::
Water Treatment Chemicals
a) Dispersants (Low molecular Weight): Co-Polymer and terpolymers of 2-Arcylamido 2-methylpropanesulfonic Acid are used in Cooling Tower and Boilers to inhibit Calcium, Magnesium and Silica scale.
b) Flocculants (High Molecular Weight): High Molecular Weight Co-polymer of 2-Arcylamido 2-methylpropanesulfonic Acid is used to percipitate solids in industrial and mining effluents.
Emulsions For Paints and Paper Coatings
Polymers containing 2-Arcylamido 2-methylpropanesulfonic Acid improve scrub resistance, dispersant performance and reduce grit formation.
Adhesives
a) Pressure Sensitive Adhesives : Ploymers containing 2-Arcylamido 2-methylpropanesulfonic Acid are used to improve tack and peel strength in Pressure Sensitive Adhesive fromulations.
b) Wood Glue : ploymers containing 2-Arcylamido 2-methylpropanesulfonic Acid improve adhesive strength, thermal and mechanical properties with superior rheology.
Hydrogels and Super absorbants
Polymers containing 2-Arcylamido 2-methylpropanesulfonic Acid are used in diapers, lotions and other personal care products, due to high water absorbing capacity, electrical conductivity, slipperiness and lubricity. Being super absorbants, ploymers also finds applications in the agriculture sector as water retention agents.
Textiler Auxillaries
Ploymers containing 2-Arcylamido 2-methylpropanesulfonic Acid are widely used as Textile Sizing Agents, Thickeners, Dispersants and Non-Woven Emulsion Binders.
Detergents and Cleaners
Polymers containing 2-Arcylamido 2-methylpropanesulfonic Acid improve charachteristic of hydrophilicity, dispersibility, and lubricity and also enhance the cleaning efficiency of Detergents and Cleaners
Oilfield and Mining Chemicals
Polymers containing 2-Arcylamido 2-methylpropanesulfonic Acid provide excellent high temperature stability, lubricity and friction reduction in drilling and cementing fluids.
Construction Chemicals / Super Plasticizers
Polymers containing 2-Arcylamido 2-methylpropanesulfonic Acid improve dispersability, lubricity and can be used as excellent flow control auxillaries for building materials.
Acrylic Fibre
Used as co-monomer in acrylic fiber industry to enhance dye receptibility.
EM35, PHPA LIQUID, GLO D RILPOL 9000, POLYPLUS,EZ MUD, NEW DRILL HP, HYDRO CAP L, HYDRO CAP RD, Poly PLUS, Liqui Pol
PHPA Emulsion is manufactured at our Mumbai plant in India. We are one of the leading manufacturers and suppliers to Oil Field , Mineral Exploration , HDD , Water Well Drilling etc. We are supplying to all major drilling companies in India and abroad.
Our other valuable products- PHPA Emulsion, PHPA Powder and Drilling Viscosifiers, Drilling Fluid Additive for Bentonite, Drilling Waste Water Treatment Chemicals, Shale Inhibitor & Clay Stabilizers, Extreme Pressure Lubricants, Coagulants, Flocculants, De Oiler, Decolorizing Polymers and Mineral Processing & Slime Treatment Polymers.
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